保温时间对BNi-2非晶钎料钎焊1Cr18Ni9Ti不锈钢接头组织和性能的影响

哈尔滨工业大学[威海] 山东省特种焊接技术重点实验室,山东 威海 264209

钎焊; 非晶钎料; 不锈钢; 微观组织; 抗剪强度

Effect of holding time on microstructure and mechanical properties of 1Cr18Ni9Ti stainless steel joint brazed by amorphous BNi-2 filler metal
FU Wei, CHEN Bin, SONG Xiaoguo, WANG Huaijin, HU Shengpeng, BIAN Hong

Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology, Weihai, Shandong 264209, China

brazing; amorphous brazing alloy; stainless steel; microstructure; shear strength

DOI: 10.3969/j.issn.1672-9374.2024.01.014

备注

对不同保温时间下1Cr18Ni9Ti不锈钢/非晶BNi-2/1Cr18Ni9Ti不锈钢钎焊接头的界面组织演变及力学性能进行探究,为制造高可靠接头提供理论支持。采用BNi-2非晶钎料箔片,在1 000 ℃不同保温时间下进行1Cr18Ni9Ti不锈钢的真空钎焊,通过SEM和EDS等表征手段分析了接头中钎料与母材之间的作用机理,对接头的抗剪强度进行评价并分析其断裂机理,探究不同保温时间下钎焊接头界面组织演化和力学性能变化规律。钎缝的主要成分为Ni(s,s)+CrB。随保温时间的增加,钎缝宽度不断减小,CrB的晶间渗入程度加剧,接头的抗剪强度先升后降,保温时间为10 min时获得最大值248 MPa。保温时间较短时,焊缝中存在的大块CrB相为裂纹源,呈脆性断裂; 延长保温时间,大块CrB变得细小,断裂位置变为扩散区,呈韧性断裂,强度提高; 当时间进一步延长,大量CrB渗入母材,母材成为薄弱区,断裂于晶间渗入区,呈脆性断裂。BNi-2非晶钎料可实现1Cr18Ni9Ti不锈钢的真空钎焊,通过改变保温时间可以调控钎料中B元素的过渡行为,进而调控焊缝组织,从而获得最佳性能接头。
This investigation explored how the interfacial microstructure and mechanical characteristic of 1Cr18Ni9Ti stainless steel/amorphous BNi-2 filler/1Cr18Ni9Ti brazed joints were affected by heat preservation time, providing theoretical support for manufacturing reliable brazed joints. Amorphous BNi-2 filler metal was used to braze 1Cr18Ni9Ti stainless steel at 1 000 ℃ for various holding time. The interaction mechanism between the filler metal and the base metal were characterized by SEM and EDS. Furthermore, testing was conducted to evaluate the shear strength of the joints and to analyze their fracture mechanism. The investigation focused on the evolution of interfacial structures and the mechanical properties of brazed joints under varying holding time. The main components of the brazing seam are mainly Ni(s,s)and CrB. With the increase of heat preservation time, the width of the brazing seams decreases and the intergranular infiltration of CrB increases. The shear strength of the joints exhibits an initial increase followed by a decrease as the holding time increases. At a holding time of 10 minutes, the shear strength of the brazed joints peaks at 248 MPa. When the holding period is short, large blocky CrB particles are distributed in the center of the brazed seam, which is the source of cracks exhibiting brittle fracture. As the holding time becomes longer, the large CrB blocks become smaller and the fracture location becomes a diffusion zone, exhibiting ductile fracture and increased strength. When the holding period is further prolonged, massive CrB permeates into the steel along the grain boundary, causing it to become a weak zone and fracture in the intergranular infiltration zone, resulting in brittle fracture. Amorphous BNi-2 filler is suitable to braze 1Cr18Ni9Ti stainless steel. By changing the holding time, the transition behavior of element B in the filler can be controlled, thereby regulating the weld microstructure and obtaining the best performance joint.
·