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[1]徐涛,李宁,贺子君,等.200 N推力装置上肼类分解催化剂的应用性能[J].火箭推进,2024,50(05):148-156.[doi:10.3969/j.issn.1672-9374.2024.05.015]
　XU Tao,LI Ning,HE Zijun,et al.Application performance of a hydrazine decomposition catalyst based on a 200 N thruster device[J].Journal of Rocket Propulsion,2024,50(05):148-156.[doi:10.3969/j.issn.1672-9374.2024.05.015]

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200 N推力装置上肼类分解催化剂的应用性能

《火箭推进》[ISSN:1672-9374/CN:CN 61-1436/V] 卷: 50 期数: 2024年05期页码: 148-156 栏目: 目次出版日期: 2024-11-13

Title:: Application performance of a hydrazine decomposition catalyst based on a 200 N thruster device

文章编号:: 1672-9374(2024)05-0148-09

作者:: 徐涛; 李宁; 贺子君; 贾勐; 张中柱; 邢钢; 赵孟超; 杜宗罡; 西安航天动力试验技术研究所,陕西西安 710100

Author(s):: XU Tao; LI Ning; HE Zijun; JIA Meng; ZHANG Zhongzhu; XING Gang; ZHAO Mengchao; DU Zonggang; Xi'an Aerospace Propulsion Test Technology Institute, Xi'an 710100, China

关键词:: 肼类分解催化剂; 单组元姿轨控发动机; 200 N推力装置; 热试考核

Keywords:: hydrazine decomposition catalyst; mono-propellant attitude and orbit control engine; 200 N thruster device; hot-firing test and assessment

分类号:: V511

DOI:: 10.3969/j.issn.1672-9374.2024.05.015

文献标志码:: A

摘要:: 研究制备了一种单组元姿轨控发动机用肼类分解催化剂,采用200 N推力装置对其应用性能进行了研究和考察。在催化剂物化性能指标满足应用要求的基础上,利用200 N推力装置通过力学环境试验考察了催化剂力学环境适应性,通过双-10 ℃低温冷启动、低温稳态及脉冲、正负拉偏以及脉冲寿命热试考核程序考察了自制催化剂的低温冷启动性能、低温稳态性能、常温正负拉偏稳态性能以及脉冲寿命性能。结果表明:该催化剂肼催化分解效率在99%以上,机械强度高且力学环境适应性良好,具有较高的肼催化分解活性和稳定性,能够在200 N推力装置上于双-10 ℃正常启动,顺利完成了低温稳态、常温正负拉偏和脉冲寿命等考核程序,发动机室压平稳,响应特性良好,脉冲一致性好,可满足推力装置的使用要求。

Abstract:: This study investigates the application performance of a hydrazine decomposition catalyst using a 200 N thruster device. On the basis that the physical and chemical properties of the catalyst meet the application requirements, the mechanical environment adaptability of the catalyst is investigated using a 200 N thruster device. The low-temperature cold start performance, low-temperature steady-state performance, normal temperature positive and negative bias steady-state performance, and pulse lifetime performance of the catalyst are also investigated. The results indicate that the catalyst has a hydrazine catalytic decomposition efficiency above 99%, excellent mechanical strength, good mechanical environment adaptability, and high hydrazine catalytic decomposition activity and stability. The test shows that the catalyst can meet the usage requirements of a 200 N thruster device.

参考文献/References:

[1] VIEIRA R, BERNHARDT P, LEDOUX M J, et al. Performance comparison of Ir/CNF and Ir/Al₂O₃ catalysts in a 2 N hydrazine microthruster[J]. Catalysis Letters, 2005, 99(3): 177-180.
[2]CHEN X W, ZHANG T, YING P L, et al. A novel catalyst for hydrazine decomposition: molybdenum carbide supported on γ-Al₂O₃[J]. Chemical Communications, 2002(3): 288-289.
[3]VIEIRA R, BASTOS-NETTO D, LEDOUX M J, et al. Hydrazine decomposition over iridium supported on carbon nanofibers composite for space applications: Near actual flight conditions tests[J]. Applied Catalysis A: General, 2005, 279(1/2): 35-40.
[4]张雄伟. 贵金属铱催化剂的制备、表征及其性能研究[D]. 成都: 四川大学, 2005.
ZHANG X W. Preparation, characterization and performance of precious metal iridium catalyst[D]. Chengdu: Sichuan University, 2005.
[5]CONTOUR J. Hydrazine decomposition over a supported iridium catalyst[J]. Journal of Catalysis, 1972, 24(3): 434-445.
[6]李令成,蓝蕴基.肼分解催化剂进展[J].工业催化,1994(1):3-7.
LI L C, LAN Y J. Progress of hydrazine decomposition catalysts[J]. Industrial Catalysis, 1994(1): 3-7.
[7]湛建阶, 陈朝辉. 肼类分解催化剂研究进展[J]. 材料导报, 2007, 21(2): 62-66.
ZHAN J J, CHEN Z H. Progress in research on hydrazine decomposition catalysts[J]. Materials Review, 2007, 21(2): 62-66.
[8]苗壮, 史建公, 郝建薇, 等. 拟薄水铝石的胶溶性与结构的关系[J]. 石油学报(石油加工), 2016, 32(3): 493-500.
MIAO Z, SHI J G, HAO J W, et al. Relationship between peptization and structure of pseudo-boehmite[J]. Acta Petrolei Sinica(Petroleum Processing Section), 2016, 32(3): 493-500.
[9]张继光. 催化剂制备过程技术[M]. 北京: 中国石化出版社, 2004.
[10]SOARES NETO T G, COBO A J G, CRUZ G M. Evolution of morphologic properties on the preparation of Ir/Al₂O₃ catalysts with high metallic contents[J]. Applied Surface Science, 2005, 240(1/2/3/4): 355-365.
[11]中国人民解放军总装备部.卫星用无水肼分解催化剂规范:GJB 8371—2015[S].北京:总装备部军标出版发行部,2015.
[12]国防科学技术工业委员会.催化剂-814和催化剂-816规范:GJB 1960—1994[S].北京:中国标准出版社,1994.
[13]SOARES NETO T G, DIAS F F, COBO A J G, et al. Evolution of textural properties and performance of Ir/Al₂O₃ catalysts during hydrazine catalytic decomposition in a 2 N satellite thruster[J]. Chemical Engineering Journal, 2011, 173(1): 220-225.
[14]孙军, 黄延强, 张涛. 纳米碳纤维/碳毡负载碳化钨和碳氮化钨的肼分解性能[J]. 化工学报, 2015, 66(8): 2976-2981.
SUN J, HUANG Y Q, ZHANG T. Catalytic performance of cabon fiber felt supported tungsten carbide and tungsten carbonitride for hydrazine decomposition[J]. CIESC Journal, 2015, 66(8): 2976-2981.
[15]DAI H B, ZHONG Y J, WANG P. Hydrogen generation from decomposition of hydrous hydrazine over Ni-Ir/CeO₂ catalyst[J]. Progress in Natural Science: Materials International, 2017, 27(1): 121-125.
[16]王学涛, 张小龙, 焦叶凡, 等. 不同载体负载的Mn系复合氧化物催化剂性能研究[J]. 锅炉技术, 2015, 46(4): 7-11.
WANG X T, ZHANG X L, JIAO Y F, et al. Study on performance of Mn-based oxide catalysts on different supports[J]. Boiler Technology, 2015, 46(4): 7-11.
[17]刘茜. 中孔氧化铝材料的合成、表征和催化应用研究[D]. 大连: 中国科学院研究生院(大连化学物理研究所), 2006.
LIU Q. Synthesis, characterization and catalytic application of mesoporous alumina materials[D]. Dalian: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 2006.
[18]KOLITCHEFF S, JOLIMAITRE E, HUGON A, et al. Tortuosity of mesoporous alumina catalyst supports: Influence of the pore network organization[J]. Microporous and Mesoporous Materials, 2017, 248: 91-98.
[19]JANJUA N K, FIRDOUS N, BHATTI A S, et al. Preparation and catalytic evaluation of Ir and Ru catalysts supported in γ-Al₂O₃ for hydrazine decomposition in a 1 N microthruster[J]. Applied Catalysis A: General, 2014, 479: 9-16.
[20]SOARES NETO T G, COBO A J G, CRUZ G M. Textural properties evolution of Ir and Ru supported on alumina catalysts during hydrazine decomposition in satellite thruster[J]. Applied Catalysis A: General, 2003, 250(2): 331-340.
[21]赵许群, 张涛, 孙孝英, 等. 肼分解催化剂的表征及失活机理研究[J]. 催化学报, 2000, 21(6): 594-596.
ZHAO X Q, ZHANG T, SUN X Y, et al. Characterization of catalyst for hydrazine decomposition and its deactivation mechanism[J]. Chinese Journal of Catalysis, 2000, 21(6): 594-596.
[22]鲍世国,公绪滨,陈艺,等.一种HAN基单元推进剂及催化分解性能研究[J].火箭推进,2018,44(2):39-45.
BAO S G,GONG X B,CHEN Y,et al. Investigation of a novel HAN-based monopropellant and its catalytic decomposition performance[J]. Journal of Rocket Propulsion,2018,44(2):39-45.
[23]JOFRE J B F, SOARES NETO T G, DIAS F F, et al. Evaluation of Ir/Al₂O₃, Ir-Ru/Al₂O₃ and Ru/Al₂O₃ catalyst performance in a 5 N satellite thruster[J]. Acta Astronautica, 2013, 85: 41-50.
[24]王镜淇,王成刚,陈雪娇,等. RBCC组合动力用液体推进剂研究进展[J].火箭推进,2022,48(6):101-112.
WANG J Q,WANG C G,CHEN X J,et al. Research progress of liquid propellant development for RBCC engine[J]. Journal of Rocket Propulsion,2022,48(6):101-112.

备注/Memo

收稿日期:2024- 01- 18修回日期:2024- 06- 16
基金项目:陕西省特种能源化学与材料重点实验室开放基金(SPCF-SKL-2021-0001)
作者简介:徐涛(1987—),男,硕士,研究领域为液体火箭推进剂。

更新日期/Last Update: 1900-01-01